Pump-Probe Photoionization Study of the Passage and Bifurcation of a Quantum Wave Packet Across an Avoided Crossing
نویسندگان
چکیده
منابع مشابه
Pump-probe photoionization study of the passage and bifurcation of a quantum wave packet across an avoided crossing.
The application of femtosecond pump-probe photoelectron spectroscopy to directly observe vibrational wave packets passing through an avoided crossing is investigated using quantum wave packet dynamics calculations. Transfer of the vibrational wave packet between diabatic electronic surfaces, bifurcation of the wave packet, and wave packet construction via nonadiabatic mixing are shown to be obs...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 2003
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.90.248303